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量子效率結果顯示，透光型非晶矽薄膜太陽能電池模組時短路電流提升0.5%，在CIGS薄膜太陽能電池模組則提升1.8%，綜合以上結果，確認薄膜確實具有抗反射與表面鈍化效果。

由 ... 資料載入處理中... 跳到主要內容 臺灣博碩士論文加值系統 ::: 網站導覽| 首頁| 關於本站| 聯絡我們| 國圖首頁| 常見問題| 操作說明 English |FB專頁 |Mobile 免費會員 登入| 註冊 功能切換導覽列 (159.65.142.206)您好！臺灣時間：2021/12/2011:01 字體大小：       ::: 詳目顯示 recordfocus 第1筆/ 共1筆  /1頁 論文基本資料 摘要 外文摘要 目次 參考文獻 電子全文 紙本論文 論文連結 QRCode 本論文永久網址: 複製永久網址Twitter研究生:江庚翰研究生(外文):Geng-HanJiang論文名稱:帶電荷高分子薄膜在薄膜太陽電池之抗反射與電性探討論文名稱(外文):Anti-reflectionpropertyandelectricalcharacteristicsofchargedpolymerlayerinthinfilmsolarcells指導教授:陳念波、黃莉媚指導教授(外文):Nien-PoChen、Lee-MayHuang口試委員:劉維昇、陳建勳口試委員(外文):Wei-ShengLiu、Jian-XunChen口試日期:2014-07-16學位類別:碩士校院名稱:元智大學系所名稱:光電工程學系學門:工程學門學類:電資工程學類論文種類:學術論文論文出版年:2014畢業學年度:102語文別:中文論文頁數:89中文關鍵詞:薄膜太陽能電池、抗反射膜、表面鈍化、逐層自組裝法、薄膜厚度、折射率、交流阻抗分析、量子效率、Zeta界面電位外文關鍵詞:Thinfilmsolarcells、Anti-reflectionfilm、Surfacepassivation、Layer-by-Layerself-assemblymethod、Filmthickness、Refractiveindex、Acimpedancemethod、Quantumefficiency、Zetapotential相關次數: 被引用:0點閱:450評分:下載:39書目收藏:0 薄膜太陽能電池具有輕薄、低成本等優點，是繼單晶太陽能電池之後，被認為是當前最具發展潛力的太陽能技術。

然而薄膜太陽能電池的發電效率目前仍不及單晶太陽能電池。

常見太陽能電池效率提升的手段為改善抗反射膜、表面鈍化、光吸收層鈍化、異質接面等，期望能在市面上與單晶太陽能電池競爭。

本論文使用浸泡式逐層自組裝法(layer-by-layerselfassembly)，利用靜電吸附原理，在薄膜太陽能電池模組上之電極處製作聚二烯丙基二甲基氯化銨(polydimethyldiallylammoniumchloride,PDDA)與二(2–羥基丙酸)二氫氧化二銨合鈦(titanium(IV)bis(ammoniumlactato)dihydroxide,TALH)雙層聚高分子薄膜，探討時將著重於帶電荷雙層聚高分子薄膜對薄膜太陽能電池之抗反射與表面鈍化效果。

分別利用光學與電學兩種分析，來探討帶電荷聚高分子薄膜抗反射與鈍化行為。

由電化學交流阻抗量測儀(electrochemicalimpedancespectroscopy,EIS)，顯示在透光型非晶矽薄膜太陽能電池模組時並聯電阻提升3.1%，在CIGS薄膜太陽能電池模組則提升8.2%，確實發現此薄膜具有明顯地表面鈍化效果。

而在光譜儀量測下，透光型非晶矽薄膜太陽能電池模組平均抗反射效果在PDDA溶液濃度1.0wt%時增加1.30%，而在CIGS薄膜太陽能電池模組平均抗反射效果在PDDA溶液濃度1wt%時也平均增加1.8%，確認薄膜確實具有抗反射效果。

量子效率結果顯示，透光型非晶矽薄膜太陽能電池模組時短路電流提升0.5%，在CIGS薄膜太陽能電池模組則提升1.8%，綜合以上結果，確認薄膜確實具有抗反射與表面鈍化效果。

由以上所有結果進行統整，確認該帶電荷雙層聚高分子薄膜同時具有表面鈍化與抗反射兩種特性，可以提升薄膜太陽能電池發電效率。

實驗結果顯示PDDA溶液浸泡時間控制在1分鐘且PDDA溶液濃度為1wt%，可得到最佳的抗反射效果。

Thin-filmsolarcellshavetheadvantagesoflightweightandlowcost.Theyarecurrentlythemostpromisingsolartechnologyaftermonocrystallinesolarcells.However,theirpowergenerationefficiencyisnotasgoodasthatofthemonocrystallinesolarcells.Toimprovetheirefficiency,somediffttacticshavebeenappliedtothethinfilmsolarcells,suchastheanti-reflectionfilmsurfacepassivation,passivationinthelight-absorbinglayer,andusingheterojunction.Inmystudy,theanti-reflectionandsurfacepassivationaresimultaneouslyachievedbygrowingtwolayersofpolydimethyldiallylammoniumchloride,PDDA,andtitanium(IV)bis(ammoniumlactato)dihydroxide,TALH,respectively,ontheelectrodesofthesolarcellmodule,bymeansoflayer-by-layerselfassembly,takingtheadvantageofelectrostaticattraction.Theelectrochemicalimpedancespectroscopy,EIS,showsthatourchargedpolymerfilmincreasetheshuntresistanceby3.1%fortheamorphoussiliconthinfilmsolarcellmodule,andby8.2%forCIGSthinfilmsolarcellmodule.Byopticalcharacterization,thefilmassociatedwith1.0wt%PDDAyield1.3%re-ductioninreflectancefortheamorphoussiliconthinfilmsolarcellmodule,and1.8%reductionforCIGSthinfilmsolarcellmodule.Byquantumefficiencymeasurement,theshortcircuitcurrentisenhancedby0.5%fortheamorphoussiliconthinfisolarcellmodule,andby1.8%forCIGSthinfilmsolarcellmodule.Insummary,thechargedpolymerduallayersachievetheanti-reflectionandsurfacepassivationsimultaneously.Themoduleswiththetreatmentyieldoptimalefficiencywithbeingsubmerged1minuteinPDDA1.0wt%solution. 書名頁.....................................................i論文口試委員審定書........................................ii授權書...................................................iii中文摘要..................................................vi英文摘要.................................................vii誌謝....................................................viii目錄......................................................ix表目錄...................................................xii圖目錄..................................................xiii一、緒論...................................................11.1研究背景...............................................11.2文獻回顧...............................................31.3研究動機與目的.........................................71.4論文架構...............................................7二、實驗原理...............................................92.1薄膜太陽能電池結構.....................................92.1.1硒化銅銦鎵薄膜太陽能電池............................102.1.2透光型非晶矽(a-Si)薄膜太陽能電池..................112.2逐層自組裝法原理......................................122.3聚高分子材料..........................................122.3.1聚二丙烯基二甲基氯化銨(PDDA).......................132.3.2二(2–羥基丙酸)二氫氧化二銨合鈦(TALH)..............142.4抗反射膜..............................................152.4.1抗反射膜原理........................................152.4.2雙層結構與反射率....................................172.5太陽能電池電性........................................182.5.1電流–電壓特性曲線..................................182.5.2太陽能電池效率......................................202.6量子效率量測..........................................232.7表面鈍化與交流阻抗量測................................232.7.1表面鈍化原理........................................242.7.2交流阻抗量測........................................25三、實驗過程與儀器........................................273.1實驗過程..............................................273.2光譜儀................................................283.3量子效率量測儀器......................................303.4掃描式電子顯微鏡/X光能量散佈分析儀/原子力顯微鏡.......303.5橢圓偏振儀............................................343.6電化學交流阻抗量測儀..................................353.7太陽光模擬量測器......................................363.8Zeta界面電位分析儀...................................37四、實驗結果與分析........................................394.1帶電荷雙層聚高分子薄膜電學特性........................404.1.1Zeta界面電位分析量測...............................404.1.2交流阻抗與漏電流量測................................414.2帶電荷雙層聚高分子薄膜光學特性........................444.2.1穿透率、反射率、吸收率特性..........................454.2.2薄膜厚度與折射率....................................634.2.3量子效率量測........................................704.3電流–電壓曲線量測....................................70五、結論..................................................75參考文獻..................................................78自傳......................................................89 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